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Caesium tungstate

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Caesium tungstate
Names
Other names
Cesium tungstate, Cesium tungsten oxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.639 Edit this at Wikidata
EC Number
  • 237-019-0
  • InChI=1S/2Cs.4O.W/q2*+1;;;2*-1;
    Key: VPXSRGLTQINCRV-UHFFFAOYSA-N
  • [O-][W](=O)(=O)[O-].[Cs+].[Cs+]
Properties
Cs2WO4
Molar mass 513.65 g/mol
Melting point >350 °C[1]
Related compounds
Other cations
Lithium tungstate
Sodium tungstate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Caesium tungstate or cesium tungstate is an inorganic chemical compound that is notable for forming a very dense liquid in solution. The solution is used in diamond processing, since diamond sinks in it, whereas most other rocks float.

Properties

Caesium tungstate forms colorless crystals, which are strongly hygroscopic. A phase transition from orthorhombic to hexagonal crystal system occurs at 536 °C.

Preparation

Caesium tungstate can be obtained by the reaction between caesium chloride (CsCl) and silver tungstate (Ag2WO4) or the reaction between tungstic acid and caesium hydroxide.

References