Samarium(III) molybdate
   
| |
| Identifiers | |
|---|---|
| Properties | |
| Sm2(MoO4)3 | |
| Appearance | white solid[1] |
| insoluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Samarium molybdate is an inorganic compound, with the chemical formula Sm2(MoO4)3. It is one of the compounds formed by the three elements samarium, molybdenum and oxygen. It can be obtained by reacting samarium nitrate and sodium molybdate in the pH range of 5.5~6.0.[2] Its single crystal can be grown at 1085 °C by the Czochralski method.[3] It can be reduced to the tetravalent molybdenum compound Sm2Mo3O9 by hydrogen at 500~650 °C.[4]
References
- ^ Q Huang, J Xu, W Li (1989-02). "Preparation of tetragonal defect scheelite-type RE2(MoO4)3 (RE=La TO Ho) by precipitation method". Solid State Ionics. 32–33: 244–249. doi:10.1016/0167-2738(89)90228-2. Archived from the original on 2022-06-18. Retrieved 2022-05-17.
{{cite journal}}: Check date values in:|date=(help)CS1 maint: multiple names: authors list (link) - ^ C. M. Gupta, M. P. Joshi (1968-05). "Investigations on Polymolybdates of Rare Earths. Electrometric Studies on the Compositions of Samarium Polymolybdate". Bulletin of the Chemical Society of Japan. 41 (5): 1268–1270. doi:10.1246/bcsj.41.1268. ISSN 0009-2673. Archived from the original on 2022-05-17. Retrieved 2022-05-17.
{{cite journal}}: Check date values in:|date=(help) - ^ Son, Jong Yoon; Lee, Sudae; Ahn, HyungJoo; Moon, Junkyu; Lee, Chanku; Jeon, Hyoseo; Lee, Hung-Bok. Behavior of ferroelastic domains in Sm2(MoO4)3 crystalsTemplate:Ko. Sae Mulli, 2001. 43 (1): 30-35. ISSN 0374-4914.
- ^ 史发年, 任玉芳, 孟建. Ln2Mo3O9的制备、结构及电磁性质. 应用化学, 1995. 2: 95-97.