Jump to content

Europium(II) hydroxide

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by Praseodymium-141 (talk | contribs) at 15:15, 25 June 2023 (Created page with '{{Chembox | Name = | ImageFile = Europium dihydroxide.png | ImageSize = | ImageAlt = | IUPACName = | OtherNames = Europium dihydroxide | Section1 = {{Chembox Identifiers | CASNo = 12020-56-3 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = | SMILES = }} | Section2 = {{Chembox Properties | Formula = Eu(OH)<sub>2</sub> | MolarMass = | Appearance = pale yellow<ref name=HB>H. Baernighausen. Lattice constants and space group of the isoty...'). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

(diff) ← Previous revision | Latest revision (diff) | Newer revision → (diff)
Europium(II) hydroxide
Names
Other names
Europium dihydroxide
Identifiers
Properties
Eu(OH)2
Appearance pale yellow[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Europium(II) hydroxide is an inorganic compound, with the chemical formula of Eu(OH)2. It can exist as the dihydrate Eu(OH)2·H2O.

Preparation

The monohydrate of europium hydroxide can be obtained by the reaction of metal europium and 10 mol/L sodium hydroxide solution.[1] There are some sources that use europium(III) chloride as a raw material, and prepare it by reacting the Jones reductor with sodium hydroxide solution.[2]

Properties

It belongs to the orthorhombic crystal system, a=6.701 ± 0.002, b=6.197 ± 0.002, c=3.652 ± 0.001 A.[1] It thermally decomposes to form europium(II) oxide (EuO); it is readily oxidized to europium(III) hydroxide in air.[3]

References

  1. ^ a b c H. Baernighausen. Lattice constants and space group of the isotypic compounds Eu(OH)​2.H2O, Sr(OH)​2.H2O, and Ba(OH)​2.H2O. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1966. 342 (5-6): 233-239. ISSN: 0044-2313.
  2. ^ Garton, G.; Hukin, D. A. Studies of some europium(II) compounds. Proc. Conf. Rare Earth Res., 3rd, Clearwater, Florida, 1964. (1963) 3-10.
  3. ^ 无机化学丛书 第七卷 钪 稀土元素. 科学出版社. pp 202, 204-205