六氟铋酸锂:修订间差异
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| NameEn = lithium hexafluorobismuthate |
| NameEn = lithium hexafluorobismuthate |
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| MolarMass = 329.91 |
| MolarMass = 329.91 |
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| Density = 4.80 g·cm<sup>−3</sup><ref>[https://www.osti.gov/biblio/1201638-materials-data-libif6-sg-materials-project Materials Data on LiBiF<sub>6</sub> (SG:148) by Materials Project]. U.S. Department of Energy Office of Scientific and Technical Information. {{doi|10.17188/1201638}}. 2014-11-02. [2020-05-20].</ref> |
| Density = <!-- 4.80 g·cm<sup>−3</sup><ref>[https://www.osti.gov/biblio/1201638-materials-data-libif6-sg-materials-project Materials Data on LiBiF<sub>6</sub> (SG:148) by Materials Project]. U.S. Department of Energy Office of Scientific and Technical Information. {{doi|10.17188/1201638}}. 2014-11-02. [2020-05-20].</ref> -->5.05 g·cm<sup>−3</sup><ref>[https://materials.springer.com/isp/crystallographic/docs/sd_1712711 LiBiF<sub>6</sub> Crystal Structure]. Springer Materials. [2020-05-20]</ref> |
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'''六氟铋酸锂'''是一种[[无机化合物]],化学式为LiBiF<sub>6</sub>。它是无色晶体,与[[六氟锑酸锂]](LiSbF<sub>6</sub>)同构。<ref name=Von>{{cite doi|10.1002/zaac.19703760305}}</ref> |
'''六氟铋酸锂'''是一种[[无机化合物]],化学式为LiBiF<sub>6</sub>。它是无色晶体,与[[六氟锑酸锂]](LiSbF<sub>6</sub>)同构。<ref name=Von>{{cite journal|journal=Zeitschrift für anorganische und allgemeine Chemie|volume=376|issue=3|language=de|issn=0044-2313|date=1970-09|pages=236–244|doi=10.1002/zaac.19703760305|url=http://doi.wiley.com/10.1002/zaac.19703760305|title=Über Alkalihexafluorobismutate(V)|accessdate=2020-05-29|author=C. Hebecker}}</ref> |
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==制备及性质== |
==制备及性质== |
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六氟铋酸锂可由[[氟化锂]]与[[五氟化铋]]在无水氟化氢中反应得到。<ref>{{cite |
六氟铋酸锂可由[[氟化锂]]与[[五氟化铋]]在无水氟化氢中反应得到。<ref>{{cite journal|journal=Journal of Fluorine Chemistry|volume=11|issue=1|language=en|date=1978-01|pages=71–85|doi=10.1016/S0022-1139(00)81599-7|url=https://linkinghub.elsevier.com/retrieve/pii/S0022113900815997|title=On the syntheses and properties of some hexafluorobismuthate (V) salts and their in the metathetical synthesis of NF+4 salts|accessdate=2020-05-29|author=Karl O. Christe, William W. Wilson, Carl J. Schack|archive-date=2018-07-01|archive-url=https://web.archive.org/web/20180701121351/https://linkinghub.elsevier.com/retrieve/pii/S0022113900815997|dead-url=no}}</ref>它也可由LiBiO<sub>2</sub>在[[氟气]]流中于450~500 °C加热得到。<ref name=Von /> |
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它对潮湿十分敏感。<ref name=Von /> |
它对潮湿十分敏感。<ref name=Von /> |
2022年3月30日 (三) 09:20的最新版本
六氟铋酸锂 | ||
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英文名 | lithium hexafluorobismuthate | |
别名 | 六氟合铋(V)酸锂 | |
识别 | ||
CAS号 | 29032-73-3 | |
性质 | ||
化学式 | LiBiF6 | |
摩尔质量 | 329.91 g·mol⁻¹ | |
密度 | 5.05 g·cm−3[1] | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
六氟铋酸锂是一种无机化合物,化学式为LiBiF6。它是无色晶体,与六氟锑酸锂(LiSbF6)同构。[2]
制备及性质
[编辑]六氟铋酸锂可由氟化锂与五氟化铋在无水氟化氢中反应得到。[3]它也可由LiBiO2在氟气流中于450~500 °C加热得到。[2]
它对潮湿十分敏感。[2]
参考文献
[编辑]- ^ LiBiF6 Crystal Structure. Springer Materials. [2020-05-20]
- ^ 2.0 2.1 2.2 C. Hebecker. Über Alkalihexafluorobismutate(V). Zeitschrift für anorganische und allgemeine Chemie. 1970-09, 376 (3): 236–244 [2020-05-29]. ISSN 0044-2313. doi:10.1002/zaac.19703760305 (德语).
- ^ Karl O. Christe, William W. Wilson, Carl J. Schack. On the syntheses and properties of some hexafluorobismuthate (V) salts and their in the metathetical synthesis of NF+4 salts. Journal of Fluorine Chemistry. 1978-01, 11 (1): 71–85 [2020-05-29]. doi:10.1016/S0022-1139(00)81599-7. (原始内容存档于2018-07-01) (英语).