四氯合铜(II)酸四甲基铵:修订间差异
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| Name = 四氯合铜(II)酸四甲基铵 |
| Name = 四氯合铜(II)酸四甲基铵 |
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| NameEn = Bis(tetramethylammonium) tetrachlorocuprate(II) |
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|CustomizedImage=[[File:2.svg]][[File:Tetramethylammonium cation.svg|76px]][[File:CuCl4 2-.svg]] |
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| OtherNames = |
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| OtherNames = 四氯铜酸四甲基铵 |
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| Section1 = {{Chembox Identifiers |
| Section1 = {{Chembox Identifiers |
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| CASNo = 15692-26-9 |
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| Formula = [(CH<sub>3</sub>)<sub>4</sub>N]<sub>2</sub>[CuCl<sub>4</sub>] |
| Formula = [(CH<sub>3</sub>)<sub>4</sub>N]<sub>2</sub>[CuCl<sub>4</sub>] |
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| Appearance = 金黄色固体<ref name=Furlani />或暗黄色固体<ref name=Puri>Puri, Jugal Kishore; Chhoker, Rajni. Synthesis and characterization of metal tribromoacetates and their alkali metal derivatives. ''Journal of Chemistry'', 2013. {{doi|10.1155/2013/392310}}.</ref> |
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| Appearance = 金黄色固体 |
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==制备== |
==制备== |
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将[[氯化铜]]的[[乙醇]]溶液和[[四甲基氯化铵]]的乙醇溶液按[[化学计量比]]混合,得到四氯合铜(II)酸四甲基铵沉淀。 |
将[[氯化铜]]的[[乙醇]]溶液和[[四甲基氯化铵]]的乙醇溶液按[[化学计量比]]混合,得到四氯合铜(II)酸四甲基铵沉淀。<ref name=Furlani>Furlani, Claudio; Morpugo, Giorgio. Properties and electronic structure of tetrahalocopper(II) complexes. ''Theoretica Chimica Acta'', 1963. 1: 102-115. {{doi|10.1007/BF00529392}}.</ref>在水溶液中的反应,通过缓慢挥发,也能得到该配合物。<ref>Sveleba, S. A.; Zhmurko, V. S.; Pankivskyi, Yu. I. Behavior of the optical birefringence in conditions of the "viscous" interaction. ''Acta Physica Polonica, A'', 2000. 97 (2): 337-348. {{doi|10.12693/APhysPolA.97.337}}.</ref> |
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==性质== |
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该配合物和[[三溴乙酸银]]在[[硝基甲烷]]中反应,生成[[氯化银]]沉淀及蓝绿色的[(CH<sub>3</sub>)<sub>4</sub>N]<sub>2</sub>[Cu(O<sub>2</sub>CCBr<sub>3</sub>)<sub>4</sub>]配合物。<ref name=Puri /> |
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==参考文献== |
==参考文献== |
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[[category:四甲基铵盐]] |
[[category:四甲基铵盐]] |
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[[Category:铜配合物]] |
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[[category:氯配合物]] |
[[category:氯配合物]] |
2022年6月26日 (日) 12:39的最新版本
四氯合铜(II)酸四甲基铵 | ||
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英文名 | Bis(tetramethylammonium) tetrachlorocuprate(II) | |
别名 | 四氯铜酸四甲基铵 | |
识别 | ||
CAS号 | 15692-26-9 | |
性质 | ||
化学式 | [(CH3)4N]2[CuCl4] | |
外观 | 金黄色固体[1]或暗黄色固体[2] | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
四氯合铜(II)酸四甲基铵是一种配位化合物,化学式为[(CH3)4N]2[CuCl4]。
制备
[编辑]将氯化铜的乙醇溶液和四甲基氯化铵的乙醇溶液按化学计量比混合,得到四氯合铜(II)酸四甲基铵沉淀。[1]在水溶液中的反应,通过缓慢挥发,也能得到该配合物。[3]
性质
[编辑]该配合物和三溴乙酸银在硝基甲烷中反应,生成氯化银沉淀及蓝绿色的[(CH3)4N]2[Cu(O2CCBr3)4]配合物。[2]
参考文献
[编辑]- ^ 1.0 1.1 Furlani, Claudio; Morpugo, Giorgio. Properties and electronic structure of tetrahalocopper(II) complexes. Theoretica Chimica Acta, 1963. 1: 102-115. doi:10.1007/BF00529392.
- ^ 2.0 2.1 Puri, Jugal Kishore; Chhoker, Rajni. Synthesis and characterization of metal tribromoacetates and their alkali metal derivatives. Journal of Chemistry, 2013. doi:10.1155/2013/392310.
- ^ Sveleba, S. A.; Zhmurko, V. S.; Pankivskyi, Yu. I. Behavior of the optical birefringence in conditions of the "viscous" interaction. Acta Physica Polonica, A, 2000. 97 (2): 337-348. doi:10.12693/APhysPolA.97.337.