碱式碳酸铅：修订间差异
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| ImageFile = basic lead carbonate.svg |
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| OtherNames = C.I. 77597 |
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| MolarMass = 775.6 |
| MolarMass = 775.6 |
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| Appearance = 无色晶体粉末 |
| Appearance = 无色晶体粉末 |
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| Density = |
| Density = 6.14 g·cm<sup>−3</sup><ref name=catalog /> |
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| MeltingPt = {{convert|400|C|K}}（分解）<ref name=catalog>"Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2020-07-04].</ref><ref>{{cite journal|journal=Acta Materialia|volume=53|issue=18|language=en|date=2005-10|pages=4903–4917|doi=10.1016/j.actamat.2005.07.007|url=https://linkinghub.elsevier.com/retrieve/pii/S1359645405004118|title=Lead and lead alloy foams|accessdate=2020-07-04|author=Andree Irretier, John Banhart|archive-date=2018-06-07|archive-url=https://web.archive.org/web/20180607161132/https://linkinghub.elsevier.com/retrieve/pii/S1359645405004118|dead-url=no}}</ref> |
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| CrystalStruct = [[六方晶系]] |
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|Section8={{Chembox Related |
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| OtherCations = [[碱式碳酸铜]] |
| OtherCations = [[碱式碳酸铜]] |
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{{铅化合物}} |
{{铅化合物}} |
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{{碳酸盐}} |
{{碳酸盐}} |
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[[ |
[[Category:二价铅化合物]] |
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[[category:碳酸盐]] |
[[category:碳酸盐]] |
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[[Category:碱式盐]] |
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2024年5月20日 (一) 07:20的最新版本
| 碱式碳酸铅 | |
|---|---|
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| 别名 | C.I. 77597 |
| 识别 | |
| CAS号 | 1319-46-6 
|
| 性质 | |
| 化学式 | Pb3(OH)2(CO3)2 |
| 摩尔质量 | 775.6 g·mol⁻¹ |
| 外观 | 无色晶体粉末 |
| 密度 | 6.14 g·cm−3[1] |
| 熔点 | 400 °C（673 K）（分解）[1][2] |
| 结构 | |
| 晶体结构 | 六方晶系 |
| 相关物质 | |
| 其他阳离子 | 碱式碳酸铜 |
| 相关化学品 | 碳酸铅 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
碱式碳酸铅是一种无机化合物，化学式为Pb3(OH)2(CO3)2，有时写作2PbCO3·Pb(OH)2。周易參同契中有句：胡粉投火中，色壞還為鉛。裡面胡粉指的是此物。
制备
[编辑]称量乙酸铅并溶于水，配制成0.1mol/L的溶液。将溶液煮沸，通入二氧化碳，析出碱式碳酸铅沉淀。其它制法还有将碳酸钠溶液加入硝酸铅溶液中，或将氯化铅或硫酸铅在碳酸钠溶液中煮沸，都能得到碱式碳酸铅。[3]
参考文献
[编辑]- ^ 1.0 1.1 "Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2020-07-04].
- ^ Andree Irretier, John Banhart. Lead and lead alloy foams. Acta Materialia. 2005-10, 53 (18): 4903–4917 [2020-07-04]. doi:10.1016/j.actamat.2005.07.007. （原始内容存档于2018-06-07） （英语）.
- ^ 朱文祥. 无机化合物制备手册. 化学工业出版社, 2006. pp 484. "【XIV-40】 碱式碳酸铅" ISBN 7-5025-8537-0
 | 这是一篇关于无机化合物的小作品。您可以通过编辑或修订扩充其内容。 |