乙基硫酸铥
| 乙基硫酸铥 | |
|---|---|
| 性质 | |
| 密度 | 2.024 g·cm−3（九水，171 K）[1] |
| 溶解性（水） | 0.1 g/mL乙醇[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
乙基硫酸铥是一种无机化合物，化学式为Tm(C2H5SO4)3，它可由硫酸二乙酯和氧化铥在358 K下水解制得。[1]在La(C2H5SO4)3·9H2O稀释下，Tm3+的晶体场参数为A20<r2>=129.8 cm-1，A40<r4>=−71.0 cm-1，A60<r6>=−28.6 cm-1，A66<r6>=432.8 cm-1。[3]
参考文献
- ^ 1.0 1.1 Gerkin, Roger E.; Reppart, William J. The structures of the lanthanide ethyl sulfate enneahydrates, M(C2H5SO4)3.9H2O [M = La-Lu (except Pm)], at 171 K. Acta Cryst. (1984) C40, 781-786. doi:10.1107/S0108270184005710
- ^ B. C. Gerstein; L. D. Jennings; F. H. Spedding. Thermal and Magnetic Study of Crystal Field Splittings in Thulium Ethylsulfate. J. Chem. Phys. 37, 1496–1508 (1962). doi:10.1063/1.1733314.
- ^ Wong, Eugene Y.; Richman, Isaac (1961). Analysis of the Absorption Spectrum and Zeeman Effect of Thulium Ethylsulphate. The Journal of Chemical Physics, 34(4), 1182. doi:10.1063/1.1731717.