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F420 plays a central role in redox reactions across diverse organisms, including archaea and bacteria, by participating in methanogenesis, antibiotic biosynthesis, DNA repair and the activation of antitubercular drugs.^[1] Its ability to carry out hydride transfer reactions is enabled by its low redox potential, which is optimized for specific biochemical pathway.^[2]

^ Purwantini, Endang; Loganathan, Usha; Mukhopadhyay, Biswarup (2018-12). Metcalf, William W. (ed.). "Coenzyme F 420 -Dependent Glucose-6-Phosphate Dehydrogenase-Coupled Polyglutamylation of Coenzyme F 420 in Mycobacteria". Journal of Bacteriology. 200 (23). doi:10.1128/JB.00375-18. ISSN 0021-9193. PMC 6222201. PMID 30249701. {{cite journal}}: Check date values in: |date= (help)CS1 maint: PMC format (link)
^ Forouhar, Farhad; Abashidze, Mariam; Xu, Huimin; Grochowski, Laura L.; Seetharaman, Jayaraman; Hussain, Munif; Kuzin, Alexandre; Chen, Yang; Zhou, Weihong; Xiao, Rong; Acton, Thomas B.; Montelione, Gaetano T.; Galinier, Anne; White, Robert H.; Tong, Liang (2008-04). "Molecular Insights into the Biosynthesis of the F420 Coenzyme". Journal of Biological Chemistry. 283 (17): 11832–11840. doi:10.1074/jbc.M710352200. PMC 2431047. PMID 18252724. {{cite journal}}: Check date values in: |date= (help)CS1 maint: PMC format (link) CS1 maint: unflagged free DOI (link)

[1] Purwantini, Endang; Loganathan, Usha; Mukhopadhyay, Biswarup (2018-12). Metcalf, William W. (ed.). "Coenzyme F 420 -Dependent Glucose-6-Phosphate Dehydrogenase-Coupled Polyglutamylation of Coenzyme F 420 in Mycobacteria". Journal of Bacteriology. 200 (23). doi:10.1128/JB.00375-18. ISSN 0021-9193. PMC 6222201. PMID 30249701. {{cite journal}}: Check date values in: |date= (help)CS1 maint: PMC format (link)

[2] Forouhar, Farhad; Abashidze, Mariam; Xu, Huimin; Grochowski, Laura L.; Seetharaman, Jayaraman; Hussain, Munif; Kuzin, Alexandre; Chen, Yang; Zhou, Weihong; Xiao, Rong; Acton, Thomas B.; Montelione, Gaetano T.; Galinier, Anne; White, Robert H.; Tong, Liang (2008-04). "Molecular Insights into the Biosynthesis of the F420 Coenzyme". Journal of Biological Chemistry. 283 (17): 11832–11840. doi:10.1074/jbc.M710352200. PMC 2431047. PMID 18252724. {{cite journal}}: Check date values in: |date= (help)CS1 maint: PMC format (link) CS1 maint: unflagged free DOI (link)

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